2/19/2023 0 Comments Reactivity of dienophiles![]() Accordingly, it was stored as a solution in chloroform.Īctivated acyclic dienes 2a- c were explored and found to be quite reactive in Diels-Alder reactions with 1 ( Table 1). 7a,b Cyclobutenone ( 1) was found to be prone to polymerization when stored in the neat state, even at very low temperatures. We developed a modified version of the Sieja protocol in which a much milder Hunsdiecker-type decarboxylation-bromination was utilized, leading to gram-scale quantities of 1. Sieja 5 had actually described a preparation of cyclobutenone 1, following a very harsh Hunsdiecker-type decarboxylation-bromination of 3-oxo-cyclobutanecarboxylic acid 6 and subsequent elimination. 3) could well represent particularly useful platforms for further elaborations (vide infra).ĭCycloadduct 3h was isolated in 40% yield in the absence of ZnCl 2. Moreover, we could foresee that the products of such Diels-Alder reactions (cf. We anticipated that perhaps the ring strain of 1 might well serve to enhance its dienophilicity relative to corresponding cyclopentenones or cyclohexenones. Remarkably, although cycloadditions of substituted cyclobutenones have been reported, 4 we were unable to find a report of a Diels-Alder reaction of the parent cyclobutenone ( 1, Table 1). 3 While both of these dienophiles are known to undergo Lewis acid catalyzed Diels-Alder cycloaddition with less activated dienes, such applications require substrates which are stable to Lewis acids. However, under strictly thermal conditions, parent cyclenones such as cyclohexenone and cyclopentenone are relatively unreactive unless the diene contains strategically placed activating groups. 2Īccess to higher levels of complexity might well be facilitated if the dienophilic double bond in a Diels-Alder reaction is already housed in an existing ring. Indeed, the Diels-Alder reaction has proven to be a valuable resource in reaching many natural products of novel architecture. 1 The 6-membered rings created through Diels-Alder technology can be substructures of relatively simple targets or may be of value in building molecules of considerable complexity. The power of the Diels-Alder cycloaddition reaction in organic synthesis is widely appreciated.
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2/19/2023 0 Comments Midi patchbay softwareNEW: new "MIDI Octaver" MIDI Transformer Items - Individual Hardware or Software Instruments and FX.Layers manage the MIDI and Audio flow for all the Items that are loaded on them. Layers allow the connection between MIDI Input Controllers and the Items. Layers - the building blocks of each Scene.You can switch freely from one Scene to another with no interruption in the sound. Scenes - recall and organize Hardware instruments presets, MIDI connections, Software plugin presets, and Music Score Attachments.When you select a Song in Camelot, you load all the resources needed to play that Song (i.e., Virtual Instruments, FX, and Audio Tracks). ![]()
2/19/2023 0 Comments Windows 10 start menuJordan (Zuo Weiming) - Simplified Chinese translationĪlan (. Loginvovchyk - Russian translation, documentation and installer Your mouse cursor will change into the resize cursor, which looks like a short line with an arrow head on each end. Once the Start menu is open, position your mouse cursor on its edge. JohnEdwa - custom skins and feature requests First, launch the Start menu by either clicking on the Start button on the taskbar or pressing the Windows key. Jcee - testing, feature requests, forum moderator Gaurav Kale - testing, feature requests and user experience consultant Here are some of the people, who made significant contributions to the Classic Shell project: If you are having problems uninstalling or upgrading Classic Shell, please read this forum post. Visit the Classic Shell forum to find custom menu skins and start buttons. The latest stable version of Classic Shell is 4.3.1 More details hereĭevelopment has been picked up by volunteers on GitHub under the name Open Shell Note: As of December 2017, Classic Shell is no longer in active development. Clicking on the folder launches the application. Caption and status bar for Internet Explorer Start Menu 10 replaces the yellow folder icons with application icons.Toolbar and status bar for Windows Explorer.Start button for Windows 7, Windows 8, Windows 8.1 and Windows 10.Find programs, settings, files and documents.Quick access to recent, frequently-used, or pinned programs.Highly customizable start menu with multiple styles and skins.There is way to reinstall Windows 10 without losing data as well.Classic Shell™ is free software that improves your productivity, enhances the usability of Windows and empowers you to use the computer the way you like it. ![]() Clean installing Windows 10 from an ISO or USB drive is another option. You can reset Windows 10 by removing everything or reset the operating system by keeping your personal files. Resetting Windows 10 by keeping your data is the last resort. There are some other paid Start menu programs are also available such as StartIsBack++ and Start10. If you want the full-screen experience on a PC, go to Settings > Personalization > Start and toggle on Use Start full screen. How to Resize Tiles on Start Menu in Windows 10. How to Change Start Menu Color and Background in Windows 10. How to Change Start Menu Size in Windows 10. At the Settings window, click/tap 'Personalization.' At the left pane of the 'Personalization' window, click 'Start. Click/tap the Start button and click/tap 'Settings' to open the Settings menu. Press the Windows Logo Key (as exhibited in the picture below) to open the menu instantly. You can determine what is contained in the Start Menu. If the Start menu is not working even after trying above mentioned workarounds, you could consider a third-party Start menu program like the free Classic Shell start menu for Windows 10. Way 2: Open Start Menu by use of Windows Logo Key. ![]() Go to the Settings app > Accounts > Family & other uses > Add someone else to this PC. You can then delete the old user account or simply keep it. In most cases, the Start menu works as it should on a new user account. If none of the above workarounds are able to open up the Start menu, you can create a new user account and use the new user account instead of the current one. Step 4: Once done, click on the Start button or press Windows logo key to see the Start menu. Replace Your Windows 10 Start Menu With these Alternatives IObit Start Menu 8 Open Shell (Classic Shell) StartIsBack Start10 Start Menu X ViStart Start. If you’re seeing some errors, please ignore them. ![]() The command might take a couple of seconds to complete. Step 3: In the PowerShell window, copy and paste the following command in the PowerShell window and ten Press Enter. ![]() Click Yes when you see the User Account Control prompt. Look for the Show app list in Start menu, Show recently added apps, and Show most used apps. Step 2: Locate powershell.exe file, right-click on it and then click Run as administrator. Head to Settings > Personalization > Start. Since Start menu is not working, open up your Windows 10 drive, and navigate to the following directory: Step 1: Run PowerShell with administrator rights. Use this PowerShell command to repair Start menu Visit our Windows 10 Start menu repair tool article to download the troubleshooter and then run the same to fix the issue. Microsoft recently released Windows 10 Start menu troubleshooter which allows you fix most of the common issues with Start menu. Right-click on the StartMenuExperienceHost.exe file and then click the End option to restart the Start menu or Start screen in Windows 10. Ending the Start process will kill the Start process and automatically restart it. Step 3: Under the Processes tab, look for Start entry, right-click on the same, and then click the End option. Step 2: Click More details to see the full-version of Task Manager. Step 1: Use Ctrl + Shift +Esc keys to open the Task Manager. 2/19/2023 0 Comments Bible analyzer for linux virus![]() īrowsersDownload ManagersFile SharingFirewalls ToolsFtp-ClientMonitoring ToolsNetworking. Īudio PlayersAudio RecorderAudio RecordersAudio ToolsCD & DVD ToolsEditing ToolsEncoders & Decoders. Īstrology/Biorhythms/MysticAstronom圜omputerDictionariesE-books & LiteratureFood & BeverageGeography. He uses the key to unlock a large gate, and makes his escape on skis.ĪctionAdventure & RoleplayArcadeBoardCards, Casino & LotteryKidsOnline Gaming. A helicopter arrives, and Bond kills the occupants, and recovers a key. In 007 - Tomorrow Never Dies, Bond begins to cross the Russian border from China into a Russian radar base, which is intercepting messages delicate in subject. Using a laser designator, Bond targets the dish and a British jet flies over, dropping an Air to Surface missile. Īctive XBasic, VB, VB DotNetC / C++ / C#Compilers & InterpretersComponent & LibrariesDatabases ManagementDebugging. Īrt Screen SaversCartoons Screen SaversClocks & AlarmsCursors & FontsIcons & SymbolNature Screen SaversOther. ģD Modeling & CADAnimationAuthoring ToolsConverters & OptimizersFont & Icon ToolsGalleryIllustration. Ĭhat & Instant MessagingDial Up & Connection ToolsE-MailFax ToolsNewsletter ManagementOther Comms ToolsPager Tools. Cancel anytime.Īccounting & FinanceBusiness ApplicationsCalculatorsDatabases ToolseCommerceEducationInventory & Barcoding. Using BitTorrent is legal, downloading copyrighted material isn’t. Crack and Bibles) File marked as fake or malicious, links removed. 2/19/2023 0 Comments Greatest hits of foreigner![]() And you get 20 of ’em on this two-CD set. OK, put it this way: All those hit songs in the ’70s and ’80s that weren’t by Journey and Styx? They were performed by Foreigner, sung by Lou Gramm and probably written by guitarist Mick Jones (no, not The Clash guy). The soaring vocals of Dennis de Young, the crunching guitars of Tommy Shaw … whoops, that was Styx. The soaring vocals of Steve Perry, the crunching guitars of Neil Schon … oh wait, that was Journey. O riginally Released: 1977 – ’87 (with one extra track from a 1992 reunion).īack Story: Ah, Foreigner. Here’s what I said about it back then (with some minor editing): Leader Mick Jones has been for many years the only founding member still involved.This came out in 2002 – or at least that’s when I got it. Foreigner is one of the world's best-selling bands of all time with worldwide sales of more than 80 million records, including 37.5 million in the US. Moonlight (1994), with Gramm back on vocals, and Can't Slow Down (2009), once again without Gramm, were not major sellers the highest chart positions were obtained in Germany, where the last album peaked at No. The band's most recent albums, Unusual Heat (1991), without Gramm, who departed due to the band's shift towards the use of synthesizers, Mr. ![]() 1 on the US Rock Tracks chart), had a large sales drop-off, only hitting the Top 10 in a few European countries with a No. 6 US and Australian hit, “Say You Will” (which also rose to No. 3, while making the Top 5 in the US and Canada.Īfter a break, Foreigner released Inside Information (1987), which despite the No. 1, and in Australia where it peaked at No. Its source album, Agent Provocateur, was the band’s most successful in the UK, Germany and some other countries in Europe, where it peaked at No. 3 in Germany and the Top 10 in numerous other countries. In 1984 Foreigner had its biggest hit single, the anthemic ballad "I Want to Know What Love Is", which topped the US, UK, Canadian and Australian charts, while hitting No. In 1982 Foreigner released its first greatest hits album, Records, which has gone on to sell 7 million copies in the US. 3 on the Rock Tracks chart and the Top 30 on the Hot 100. 2 in both the US (for a record 10 weeks) and Canada, topped the US Rock Tracks chart and became their first Top 10 hit in the UK and Australia and "Juke Box Hero" reached No. 4 on the US Hot 100 and became their first Top 15 hit in Germany the ballad “Waiting for a Girl Like You” peaked at No. 1 in Canada and on the new US Rock Tracks chart, rose to No. Three of 4’s singles were hits: "Urgent" reached No. 2 in Canada, while becoming Foreigner’s break-through album outside of North America, going Top 5 in the UK, Germany and Australia. Reduced to a quartet, their album 4 (1981) hit No. 5 in North America producing two Top 20 singles, including its titletrack. Foreigner’s third album, Head Games (1979), went to No. 3 hit in both countries, and the title track, a US No. 3 in North America with two hit singles, “Hot Blooded” a No. ![]() Their 1978 follow-up, Double Vision, was even more successful peaking at No. 4 on the US album chart and in the Top 10 in Canada and Australia, while yielding two Top 10 hits in North America, "Feels Like the First Time" and "Cold as Ice". In 1977 Foreigner released its self-titled debut album, the first of four straight albums to be certified at least 5x platinum in the US. Jones came up with the band's name as he, McDonald and Dennis Elliott were British, whereas Gramm, Al Greenwood and Ed Gagliardi were American. I Want to Know What Love Is - 1999 Remasterįoreigner is a British-American rock band, originally formed in New York City in 1976 by veteran British guitarist and songwriter Mick Jones and fellow Briton and ex-King Crimson member Ian McDonald, along with American vocalist Lou Gramm. Without further ado, here are Foreigner top 10 tracks of all time: 1. Follow Foreigner to get alerts about upcoming events and special deals! Followįoreigner is a British-American rock band, originally formed in New York City in 1976 by veteran British guitarist and songwriter Mick Jones and fellow Briton and ex-King Crimson member Ian McDonald, along with American vocalist Lou Gramm.įoreigner has performed in venues such as:ģArena, Abraham Chavez Theatre, AO Arena, Blossom Music Center, Bon Secours Wellness Arena, Brandon Amphitheater, The Capitol Theatre, The Cynthia Woods Mitchell Pavilion, Dos Equis Pavilion, DTE Energy Music TheatreĭTE Energy Music Theatre, Pine Knob Music Theatre, Ford Idaho Center, Grand Sierra Resort, Hard Rock Live at Etess Arena, Wind Creek Event Center, Seminole Hard Rock 2/19/2023 0 Comments Mirage movie![]() ![]() But that’s a big appeal of such time-travel/not-space-travel stories, the back-engineering involved. “Mirage” takes its sweet time introducing those various wrinkles and seeing to it that too much is tidied up, folded in on itself. Is this all in Vera’s head, a novel that’s gotten into her brain and taken over her life? Is she just a fictional character in that story? There’s even a hint of romance, of lovelife paths not taken, delivered in flashbacks. The script also tosses in lots and lots of twists, this thread making us question this peripheral character’s actions, that one connecting another character to the past and present in ways we don’t see. Suspense comes from scenes where we see a little boy trying to reason out how to prevent a murder, or prevent the murderer from covering his tracks. She must learn all she can about Nico and what might have changed and figure out how to correct this and get her daughter back, with pretty much nobody in her current timeline helping her or even taking her seriously. And Vera finds herself spilling her story to a sympathetic cop ( Chino Darín), getting brain scans, talking to doctors and others about this recent novel that follows the plot of the story she’s telling.Īnd Vera, who was a nurse before, stayed in med school to become a neurosurgeon in this timeline, even if no one in their right mind would let her open a skull in her present (doesn’t remember finishing med school) state. Nobody knows a “Gloria.” Dashing into her husband’s office, he doesn’t recognize her. ![]() And damned if her pleas don’t save his life.īut when Vera wakes up the next day, she can’t pick up her kid from school. When Vera reaches out again during a storm that mimics the one Nico lived through that night in 1989, she manages to warn the confused and frightened child. When she Internet searches the child, she discovers a murder Nico stumbled into that very night, a murderer foiled in the act of disposing of his wife’s body, a discovery that cost Nico his life. Vera is chilled to the marrow, as are we, the moment young Nico stares into his set and speaks to her. In his timeline, the kid is keeping himself entertained while his single-mom is at work, and all that’s on TV news is the collapse of the Berlin Wall. And in the middle of a thunderstorm, Vera sees it flicker to life with images of a tween ( Julio Bohigas-Couto) practicing Cyndi Lauper’s “Time After Time” on his guitar. Tucked in an attic, they find a pre-HD cathode ray tube (analog) TV and VCR. Vera ( Adriana Ugarte), husband David ( Álvaro Morte) have just moved into a house with their little girl. “The flight of a butterfly can be very cruel if it occurs in a place and a time that allows for change,” a character muses in this story (titled “Durante la tormenta” in Spanish), long after we’ve figured out what we’re witnessing is a Spanish tale wrapped up in “ the butterfly effect.” But the mystery at the heart of it is fascinating and unraveling it is suspenseful, with life-and-death stakes that go beyond merely preventing a murder. Oriol Paulo’s Barcelona-set thriller burns more screen time with characters trying to reason out the impossible than it should, and dawdles in other ways. It’s why films like this year’s “The Call” or “Frequency,” “The Time Traveler’s Wife” or “Somewhere in Time” should never bog themselves down in “explaining” how a woman moving into a house gets calls from somebody murdered there years before, or a son finds a radio that lets him talk to his dead dad, or why a woman is able to converse with a kid via his CRT TV and camcorder in 1989 and prevent his death in “Mirage.” Movies that bend the laws of space-time without the introduction of a black hole fall more into the realm of fantasy than “Interstellar” science fiction. 2/19/2023 0 Comments Soundflower mac uninstall![]() I recently realized that there are two Libraries in the Mac, and I was searching the wrong one. (Ive been frustrated by other advice that told me to remove something from the Library. Drag the soundflower.kext file into the trash. Soundflower for Mac Download Free (2020 Latest Version). 100 Safe and Secure Allows applications to pass audio to other applications. Download Soundflower 2.0 Beta 2 for Mac from. ![]() Easy guide to setup and route computer audio for recording. Go to the System Library and find the Extensions folder. Soundflower for MAC This app was build by Soundflower Team and updated into the last version at March, 29th 2019. Sophisticated real-time, low latency routing of audio and MIDI data between apps. 274, New, Uninstall soundflower driver Type-Defect Priority-Medium. Does Soundflower Work on Windows? Alternatives to Soundflower for Mac with any license JACK Audio Connection Kit. 278, New, Soundflower wont install on Mac OSX 10.10.3 Type-Defect Priority-Medium. It works to pass audio content between a number of different applications and allows users to send live audio content into the Mixlr app from applications like Traktor and Ableton Live. What is Soundflower? The software is a special utility that has been created free of charge for Mac users. Generally, people are more attracted to open source projects as they don’t have to do any payment for this. It doesn’t require any type of extra support for sending and receiving the audio. Soundflower is a type of system extension which involves the extension for your channel audio from one application to another one. It records sound files in high-quality audio formats SWF Movie Player latest version: Free flash movie player for Mac OS uninstall soundflower mac More than 14 alternatives to choose: Audacity, eqMac2, Boom 2 and more Renoise for Mac, free and safe download Renoise for Mac, free and safe download. It comes with an easy-to-use menu bar app that allows you to configure the settings and send the audio signal to specific devices. If anyone knows what the heck is going on, your help would be much appreciated.Soundflower is a macOS kernel extension that creates virtual audio input and output devices which can be used to transfer a sound signal between various applications. Not sure if its related at all but I thought I would mention it. The other day, there was a red light shining or blinking (I dont remember) from out of the audio jack when it was closed and charging. The speakers also make a very quiet popping sound, only hearable when right up next to them, It doesnt change when volume is changed. Doing so executes the script and removes the existing driver. Press the play button at the top of the window. Open up the downloaded DMG file, and run the script highlighted below. There is also a useful tool for Mac called NDI Syphon which can. Uninstall Soundflower via Package The first step is to Download version Soundflower 1.6.6b. If run on different machines, then NDI can be used to stream the video between the two machines. ![]() I checked the Microphone input for the built in mic and it shows full bars, telling me its always picking up sound, which it is not. Character Animator 3.2 (at least) can output Syphon directly on Mac, so running Character Animator and the video conferencing software on the same machine does not require NDI. But when I went to try an audio test, they quit again. Recently I installed windows with the same result with the audio.īut when I turned it on and went into windows, the youtube video I had up last night was playing through my speakers. The speakers didnt work, 3.5mm jack didnt work and when I went into the audio settings, there was no devices shown. After I did that, the macbook shut down and when I booted it back up, it had no audio. A while ago I thought I blew up the audio chip in my macbook as I put too much signal through it. Players can play in either single-player mode or multiplayer mode with up to 6 other people by joining the same server created. ![]() The game features an impressive graphics engine allowing players to explore their worlds with no restrictions on size or placement within the game world. Collect power-ups and combos while finishing each level as quickly as possible to get the most points possible! Geometry dash Subzero is a fun-filled 3D arcade-style of soccer with an infinite number of levels for players to conquer. You can also play cooperatively with friends or complete challenges that could earn you rewards! The game features an impressive graphics engine allowing players to explore their worlds with no restrictions on size or placement within the game world. ![]() Play the game as you push your way through to new levels while avoiding obstacles in your way. Geometry Dash SubZero is a fun and addicting game based around the gameplay of RC Soccer, Geometry Dash, and Crash Bandicoot combined. At the end of this article, you will find our how-to steps which you can follow to install and run Geometry Dash SubZero on PC or MAC. However, if you ever wanted to run Geometry Dash SubZero on Windows PC or MAC you can do so using an Android emulator. ![]() RobTop Games published Geometry Dash SubZero for Android operating system(os) mobile devices. Free download Geometry Dash SubZero for PC Windows or MAC from BrowserCam. 2/19/2023 0 Comments Digital lesson planner template![]() This is done through the use of lesson plan templates. Additionally, with new technology, computers can also be a great tool to help a teacher with their lesson plan outlines. Lesson plans help teachers to stay on task as they shape and guide students through the learning process.īecause of the advancements in technology, many teachers use computers aides to work with their students. In order to ensure the educating is done correctly, effective teachers often use study plans and lesson plans as an important classroom lesson guide tool. This is done in order to ensure their students grasp the multi-layer concepts that permeate these subjects. This type of lesson planning can be of particular importance with some of the more complex areas of study, such as math and the sciences.īecause math and the sciences are filled with many differing facets, a teacher of these areas of study must ensure that they cover all the basic areas of learning before exploring the more fringe aspects of learning. ![]() Much of the success of a student can be attributed to a teacher’s planning of educational lessons which can be a critical factor in their ability to stay on task and work in with paced incremental learning styles. This is typically an environment where students can discover, theorize, thrive and excel. While many teachers can teach almost all material, it takes a teacher with excellent communication skills, good material, and proper implementation to make a classroom a positive learning environment. Using the Math Lesson Plan Template for Your Arithmetic Instruction The math lesson plan template from provides a vehicle for this planning, all from an easy-to-use and absolutely free spreadsheet. However, being a successful teacher takes time, effort, planning, and a great deal effective student connections. Working with students and watching them excel under the guidance and lessons from a teacher is often one of the best parts of the job. This is why being a teacher can be one of the most rewarding careers. Much of this has to do with the teachers who help students of all ages along their path of education. ![]() But there certainly is a difference between a good education and a mediocre one. An education is the basis of a lifetime of skills that every person needs to succeed. 2/19/2023 0 Comments China cat sunflower songI wrote it in different settings and added this andthat to it. 29) Hunter says: " 'China Cat' took a long time to write. In an interview in Golden Road (Spring, 1991, p. It's good that a few things in this world are clear to allof us." People seem to know exactly whatI'm talking about. In his Box of Rain, Hunter writes: "Nobody ever asked me the meaning of this song. 24), Hunter said: "Ican sit right here and write you a China Cat or one of those things in tenminutes.How many of those things do you need.?" Ken covers the song in their live performances. If you have time, check out my China Cat page, which (of course) featuresa direct link to your China Cat Sunflower page. By 1979 we hadreleased a single on Atlantis Records of LA and were getting lots of airplay in the SF Bay Area market.the name China Cat was well-exposedduring that period. The Dead were a big influence.īut wait, there's more. Since i was the bass player (and one ofthe creative forces in that band) I worked into our songs a lot ofsyncopation. IN addition, we covered a few Dead arrangements of cover songs(Know You Rider, Not Fade Away). During the period of 1971-72and then again between 19 I was in a Bay Area band calledChina Cat, the name adopted by myself as a direct result of my love thatDead song. ![]() This ispurely a piece of trivia-with-a-small-T. 2.Īn enduring song in the band's repertoire, usually paired with "I Know YouRider" in concert, leading to the designation "China/Rider."Ī reader writes: Date: Mon, 13:51:32 -0700Īnyway, this message is in reference to China Cat Sunflower. Grateful Dead: Authentic Guitar Classics Vol. ![]() Hunter has posted the manuscript of an early draft of the song in his archives. Look for awhile at the China Cat Sunflower The Annotated "China Cat Sunflower" "A leaf of all colors plays a golden-stringed fiddle." The Annotated "China Cat Sunflower"An installment in the Annotated Grateful Dead Lyrics.ġ997-1998 Research Associate, Music Dept., University of California Santa CruzĬhina Cat SunflowerWords by Robert Hunter music by Jerry GarciaĬopyright Ice Nine Publishing used by permission. |
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